(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

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(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

Chiral Catalysts, Ligands, Reagents, Kinetic Resolution, Privileged Ligands and Complexes, Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, SALENs, Fluorination Catalysts and Ligands, Synthetic Reagents, Fluorination Reagents

CAS Number #138124-32-0
Synonyms (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride, 98%, (R,R)-Jacobsen Catalyst
Molecular Formula C36H52ClMnN2O2

MDL Number MFCD02101664
Chemical Name (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Molecular Weight 635.2
Melting Point 330 - 332 °C
Packaging 1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.
Color Dark Brown

Applications : (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride can be  used as a catalyst for asymmetric epoxidation of unfunctionalized olefins,  asymmetric α-hydroxylation of silyl enol ethers, and synthesis of the taxol side chain,and cis-1-amino-2-indanol (which is used in the preparation of a series of potent HIV-1 protease inhibitory peptides)

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